Chapter 22. The trinitrate ester of glycerol (nitroglycerin) is an important but shock-sensitive explosive: Dynamite is a much safer and more controllable explosive, and is made by absorbing nitroglycerin in porous material such as sawdust or diatomaceous earth. d. Individual Thio-Sugars Reducing Trisaccharides c. Deuterated Carbohydrates

However, due to transit disruptions in some geographies, deliveries may be delayed. Teichoic Acids and Related Compounds Reducing Disaccharides 8. a. Thio-Sugars The reactions and derivatives of alditols are also covered.

d. Complex Polysaccharides Unless otherwise noted, LibreTexts content is licensed by CC BY-NC-SA 3.0. [ "article:topic", "osmium tetroxide", "showtoc:no" ]. - Download and start reading immediately. copying, pasting, and printing. d. Branched-Chain Derivatives of Hexoses Tetrasaccharides We value your input. p. Aldobiuronic Acids Occurrence, Detection and General Reactions Reducing Tetrasaccharides It discusses oligosaccharides and polysaccharides and related compounds.Some of the topics covered in the book are the nomenclature, stereochemistry, and structural representation of alcohols; preparations, chromatographic separation, and synthesis of alditols; conformational analysis of monosaccharide; functional derivatives of monosaccharide; and natural sources and properties of glycosides. Dianhydroalditols 5.

General Properties and Reactions

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Reactions and Derivatives of the Alditols Penta-, Hexa- and Higher Polyhydric Alcohols c. Nitrogen-Containing Trisaccharides a. Glycals or 1,2-Dideoxy-1-Enoses Individual Alditols a. Pentitols b. Hexitols c. Heptitols and Higher Alditols 3. There’s no activation 2. Scientific Journals and Periodicals d. Separation, Identification and Estimation of Monosaccharides by Chromatography and Related Techniques Occurrence Missed the LibreFest?

d. 4-Enoses (Non-Terminal)

d. Acidic Trisaccharides

2. 8. c. Cyclic Acetals and Ketals - Buy once, receive and download all available eBook formats,

c. Acidic Tetrasaccharides

b. Aminodeoxyalditols It also is used as a solvent and as an intermediate in the production of polymers (polyesters) and other products (Chapter 29).

c. Methods of Preparation Isolation and Purification 4. 1. a. Glycosides

d. Hexosylpentoses, C11H20O10

Easily read a. d. 3-Amino-3-Deoxyaldoses Deoxyalditols b. Pentosylpentoses, C10H18O9, and Their Polymer Homologues Have questions or comments? c. Polyuronides Preparation and Synthesis of Alditols c. Chromatographic Separation of Alditols 2.

Synthesis j. Nonulosaminic Acids 500 e. Esters Preface Ethylene glycol has important commercial uses.

i. Aminoketoses

Determination of Structure

Thanks in advance for your time. Please enter a star rating for this review, Please fill out all of the mandatory (*) fields, One or more of your answers does not meet the required criteria. Polysaccharides c. Deoxyhexosylpentose, C11H20O9 eBooks on smart phones, computers, or any eBook readers, including Isotopically Labeled Carbohydrates Oligosaccharides, Polysaccharides and Related Compounds d. Etherification 3. Legal. Monosaccharides Methylene glycol is reasonably stable in water solution, but attempts to isolate it lead only to its dehydration product, methanal (formaldehyde): This behavior is rather typical of gem-diols (gem \(=\) geminal, that is, with both hydroxyl groups on the same carbon atom). General Introduction a. Branched-Chain Derivatives of Tetroses i. Oxidation of Monosaccharides b. Glycoproteins of Bacterial Origin Chapter 23. b. Non-Reducing Tetrasaccharides

a. Synthesis and Methods of Preparation Glycolipids o. Nitrogen-Containing Disaccharides Polyhydric alcohols in which the hydroxyl groups are situated on different carbons are relatively stable, and, as we might expect for substances with multiple polar groups, they have high boiling … 15.8: Polyhydric Alcohols - Chemistry LibreTexts Share your review so everyone else can enjoy it too.

f. Hexosyldideoxyhexoses, C12H22O9 2,3-Dideoxy-2-Enoses 8. e. 4- and 5-Enoses (Terminal) b. Your review was sent successfully and is now waiting for our team to publish it. We are always looking for ways to improve customer experience on Elsevier.com. VitalSource Bookshelf gives you access to content when, where, and how you want. The polyhydric alcohols (polyols) may be divided into two classes, depending on whether or not they possess a ring structure. f. 5-Amino-5-Deoxyaldoses The term “glycol” indicates a diol, which is a substance with two alcoholic hydroxyl groups. Oligosaccharides 4. b. Tritium-Labeled Carbohydrates 7. The few gem-diols of this kind that can be isolated are those that carry strongly electron-attracting substituents such as the following: Polyhydric alcohols in which the hydroxyl groups are situated on different carbons are relatively stable, and, as we might expect for substances with multiple polar groups, they have high boiling points and considerable water solubility, but low solubility in nonpolar solvents: 1,2-Diols are prepared from alkenes by oxidation with reagents such as osmium tetroxide, potassium permanganate, or hydrogen peroxide (Section 11-7C). f. Natural Sources, Properties of Individual Monosaccharides and Their Derivatives c. Identification and Structural Determination of Monosaccharides by Physical Methods Determination of Structure The book can provide useful information to chemists, students, and researchers. Individual Alditols a.

Sulphur-Containing Derivatives of the Alditols b. Monosaccharide Ethers e. Synthesis of Monosaccharides List of Common Abbreviations and Symbols Used 1. The major present source is by synthesis from propene (Section 14-3A). Amino-Sugars d. Individual Deoxy-Sugars c. Esterification b.

For more information contact us at info@libretexts.org or check out our status page at https://status.libretexts.org. a. Functional Derivatives of Monosaccharides 6. Penta-, Hexa- and Higher Polyhydric Alcohols 1. The simplest example of an alcohol with more than one hydroxyl group is methanediol or methylene glycol, \(\ce{HOCH_2OH}\). n. Glycosides of Polyhydric Alcohols please, Aliphatic Compounds: Penta- and Higher Polyhydric Alcohols; Their Oxidation Products and Derivatives; Saccharides. b. Branched-Chain Derivatives of Pentoses 9. We cannot process tax exempt orders online. i. Deoxyhexosylhexoses, C12H22O10 Access online or offline, on mobile or desktop devices, Bookmarks, highlights and notes sync across all your devices, Smart study tools such as note sharing and subscription, review mode, and Microsoft OneNote integration, Search and navigate content across your entire Bookshelf library, Interactive notebook and read-aloud functionality, Look up additional information online by highlighting a word or phrase. a. 6. When you read an eBook on VitalSource Bookshelf, enjoy such features as: Personal information is secured with SSL technology. Glycerol, as a constituent of fats and lipids, plays an important role in animal metabolism. If you wish to place a tax exempt order b. Hexosans The trihydric alcohol, 1,2,3-propanetriol (glycerol), is a nontoxic, water-soluble, viscous, hygroscopic liquid that is used widely as a humectant (moistening agent). 5. COVID-19 Update: We are currently shipping orders daily. 7. f. Functional Nitrogenous Derivatives of Monosaccharides

Monoanhydroalditols 1.

Kindle. 3. Dynamite has largely been replaced by cheaper explosives containing ammonium nitrate as the principal ingredient.

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